You will need to remove the user as an approver from bills they have outstanding, before you can deactivate them.
To remove the user as an approver on the bill(s)
Click the Payables tab Bills.
Click the Waiting for Approval link.
In the Approver field, select the user.
Click the bill's Invoice #.
At the bottom of the bill Summary, find the Approver.
Delete the approver by clicking [del].
Repeat steps 1-6 for all unapproved bills for that user.
Delete the user.
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